Issue 92, 2016, Issue in Progress
From the journal:

RSC Advances

Photo-induced SI-ATRP for the synthesis of photoclickable intercalated clay nanofillers†

V.-S. Vo,ab   S. Mahouche-Chergui,*a   J. Babinot,a   V.-H. Nguyen,b   S. Nailib  and  B. Carbonnier*a  

* Corresponding authors

a Université Paris-Est, ICMPE (UMR7182), CNRS, UPEC, Thiais, France
E-mail: carbonnier@icmpe.cnrs.fr, mahouche-chergui@icmpe.cnrs.fr

b Université Paris-Est, Laboratoire Modélisation et Simulation Multi-Echelle, MSME UMR 8208 CNRS, Créteil Cedex, France

Abstract

In situ photoinduced SI-ATRP is reported as a novel and efficient route for preparing intercalated nano-clay fillers bearing clickable functions. Poly(propargyl methacrylate) chains are grown inside the clay interlayer after silanisation and grafting of bromine ATRP initiator. The generic clickable character is demonstrated through grafting with azidomethyl benzene and mercaptosuccinic acid via photodriven 1,3-dipolar cycloaddition and thiol-yne click reactions, respectively.

Graphical abstract: Photo-induced SI-ATRP for the synthesis of photoclickable intercalated clay nanofillers

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Article information

DOI
https://doi.org/10.1039/C6RA14724K
Article type
Communication
Submitted
06 Jun 2016
Accepted
10 Sep 2016
First published
12 Sep 2016

RSC Adv., 2016,6, 89322-89327

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Photo-induced SI-ATRP for the synthesis of photoclickable intercalated clay nanofillers

V.-S. Vo, S. Mahouche-Chergui, J. Babinot, V.-H. Nguyen, S. Naili and B. Carbonnier, RSC Adv., 2016, 6, 89322 DOI: 10.1039/C6RA14724K

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